Oxidative Addition of 2‐Halogenopyridines and 2‐Chloroquinoline to Zero‐Valent Group 10 Metals
نویسندگان
چکیده
منابع مشابه
Bicyclic dinuclear tris-(ditopic diphosphane) complexes of zerovalent group 10 metals†
Selective formation of bimetallic group 10 complexes using the Cs symmetric, bicyclic diphosphane P2C12H20 is reported herein. With its eclipsed lone pairs disposed at a relative angle of ca. 45 , the diphosphane framework is ideally suited to form multiple bridges between two metal centers. The complexes contain {M2P6} cages with three diphosphane bridges and a pair of trans-axial ligands such...
متن کاملCatalytic Addition of Simple Alkenes to Carbonyl Compounds Using Group 10 Metals.
Recent advances using nickel complexes in the activation of unactivated monosubstituted olefins for catalytic intermolecular carbon-carbon bond-forming reactions with carbonyl compounds, such as simple aldehydes, isocyanates, and conjugated aldehydes and ketones, are discussed. In these reactions, the olefins function as vinyl- and allylmetal equivalents, providing a new strategy for organic sy...
متن کاملOxidative addition of disulfide/diselenide to group 10 metal(0) and in situ functionalization to form neutral thiasalen/selenasalen group 10 metal(II) complexes.
Three components, one pot synthesis of thiasalen/selenasalen Ni(II), Pd(II) and Pt(II) complexes, 14-19, by the oxidative addition of S-S/Se-Se bond of bis(o-formylphenyl)disulfide/-diselenide to Ni(0), Pd(0) and Pt(0) followed by in situ Schiff base formation with ethylenediamine is reported. S-S or Se-Se bonds were cleaved and coordinated to the metal center as thiolate (ArS(-)) or selenolate...
متن کاملfaculty of psychology and social sciences group of anthropology master thesis in major of anthropology
چکیده پایان نامه (شامل خلاصه، اهداف، روش های اجرا و نتایج به دست آمده): کار جمع آوری گو یش های محلی در سال های اخیر شتاب امیدوار کننده ای به خود گرفته است. شاید از بارزترین اهداف جمع آوری گویش های مختلف، ثبت و ضبط آن، جلوگیری از نابودی و مهمتر از همه حل مشکلات دستوری زبان رسمی باشد. دقت در فرآیند های زبانی گویش های محلی نوع ارتباط مردم نواحی مختلف با پیرامون نشان را به ما نشان خواهد داد. از س...
Chemical intercalation of zerovalent metals into 2D layered Bi2Se3 nanoribbons.
We have developed a chemical method to intercalate a variety of zerovalent metal atoms into two-dimensional (2D) layered Bi(2)Se(3) chalcogenide nanoribbons. We use a chemical reaction, such as a disproportionation redox reaction, to generate dilute zerovalent metal atoms in a refluxing solution, which intercalate into the layered Bi(2)Se(3) structure. The zerovalent nature of the intercalant a...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2020
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.202000279